Vol. 19 No. 2 (2020): Mapana Journal of Sciences
Research Articles

Synthesis and characterization of penta-coordinated 2- and 4-substituted pyridine N-oxide silicon complexes

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  • Rajesh B R D Yamajala
Rajesh B R D Yamajala
Department of Chemistry, SASTRA Deemed University
Bio
DOI: https://doi.org/10.12723/mjs.53.2

Published 2020-04-01

Keywords

  • Silicon Pincolate,
  • Pyridine N-oxides,
  • Penta-coordination,
  • 29Si NMR

Copyright (c) 2020

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Abstract

Novel penta-coordinated 2- and 4-substituted pyridine N-oxide silicon complexes were synthesized by the reaction of various 2- and 4-substituted pyridine N-oxides with silicon pinacolate. These complexes were characterized by 29Si NMR, 1H NMR and 13C NMR spectroscopy. The objectives of the present work is the study of influence of substitution at either 4 or 2-position of the pyridine N-oxide on the effect of the profile of pentacoordination.

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