Cu(II), Cd(II) and Ni(II) Complexes of 5-Bromosalicylaldehyde-4-hydroxybenzhydrazone: Synthesis and Spectral Studies
DOI:
https://doi.org/10.12723/mjs.41.1Keywords:
5-Bromosalicylaldehyde-4-hydroxybenzhydrazone, Coordination Chemistry, Aroylhydrazone, LigandAbstract
Four complexes of 5-bromosalicylaldehyde-4-hydroxybenzhydrazone were synthesized and characterized by elemental analyses, electronic, and infrared spectra. In all complexes, hydrazone exists either in the neutral form, deprotonated monoanionic form or in dideprononated dianionic form. Structures were assigned to all the complexes based on the physico-chemical studies.
References
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[5] J.Y. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.T. Nguyen and J.T. Hupp, ``Metal–organic framework materials as catalysts,’’ Chem. Soc. Rev. vol. 38, no. 5, pp. 1450-1459, 2009.
[6] D.P. Singh, D.S. Raghuvanshi, K.N. Singh and V.P. Singh, ``Synthesis, characterization and catalytic application of some novel binuclear transition metal complexes of bis-(2-acetylthiophene) oxaloyldihydrazone for C N bond formation,’’ J. Mol. Catal. A: Chem. vol. 379, pp. 21-29, Nov 2013.
[7] V.P. Singh, K. Tiwari, M. Mishra, N. Srivastava and S. Saha, ``5-[{(2-Hydroxynaphthalen-1-yl) methylene} amino] pyrmidine-2, 4 (1H, 3H)-dione as Al 3+ selective colorimetric and fluorescent chemosensor,’’ Sens. Actuators, B: Chem., vol. 182, pp. 546-554, Jun 2013.
[8] A. Sahana, A. Banerjee, S. Das, S. Lohar, D. Karak, B. Sarkar, S.K. Mukhopadhyay, A.K. Mukherjee and D.Das, ``A naphthalene-based Al 3+ selective fluorescent sensor for living cell imaging,’’ Org. Bio. Chem. vol. 9, no. 15, pp. 5523-5529, 2011.
[9] A.S. Fouda, M.M. Gouda and S.I. Abd El-Rahman, ``2-Hydroxyacetophenone-aroyl hydrazone derivatives as corrosion inhibitors for copper dissolution in nitric acid solution.’’ Bull. Korean Chem. Soc., vol. 21, no. 11, pp. 1085-1089, 2000.
[10] D.E. Wilcox, ``Binuclear metallohydrolases,’ Chem. Rev., vol. 96, no. 7, pp. 2435-2458, Nov. 1996.
[11] S.R. Sheeja, N.A. Mangalam, M.R.P. Kurup, Y.S. Mary, K. Raju, H.T. Varghese and C.Y. Panicker, ``Vibrational spectroscopic studies and computational study of quinoline-2-carbaldehyde benzoyl hydrazone,’’ J. Mol. Struct. vol. 973, no. 1, pp. 36-46, Jun 2010.
[12] D. Kuriakose, A. A. Aravindakshan and M.R.P. Kurup, ``Synthesis, spectroscopic, crystal structures and photoluminescence studies of cadmium (II) complexes derived from di-2-pyridyl ketone benzoylhydrazone: Crystal structure of a rare eight coordinate cadmium (II) complex,’’ Polyhedron, vol. 127, pp. 84-96, May 2017.
[13] N. Mathew, M. Sithambaresan and M.R.P Kurup, ``Spectral studies of copper (II) complexes of tridentate acylhydrazone ligands with heterocyclic compounds as coligands: X-ray crystal structure of one acylhydrazone copper (II) complex,’’ Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 79, no. 5, pp. 1154-1161, Sep 2011.
[14] N.A. Mangalam, S. Sivakumar, M.R.P Kurup and E. Suresh, ``Design and characterization of Cu (II) complexes from 2-benzoylpyridine benzhydrazone: Crystallographic evidence for coordination versatility,’’ Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 75, no. 2, pp. 686–692, Feb 2010.
[15] N.A. Mangalam and M.R.P. Kurup, ``Versatile binding properties of a di-2-pyridyl ketone nicotinoylhydrazone ligand: Crystal structure of a Cu (II) complex,’’ Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 78, no. 3, pp. 926–934, Mar 2011.
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