Research Articles
Synthesis, Spectral and Magnetic Properties of Ternary Nickel (II) Complexes with Acid Hydrazones and Heterocyclic Bases
Published 2021-08-27
Keywords
- NiII complexes,
- Acid hydrazones,
- pseudo octahedral,
- magnetic susceptibility,
- ternary complexes
Copyright (c) 2012
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Abstract
A series of nickel(II) complexes have been synthesized by the reaction of nickel(II) acetate with some hydrazones in presences of heterocyclic bases like 2 2’-bipyridine and 1, 10- phenanthroline and characterized by analytical and other spectral techniques, like IR, far IR, and UV-Vis spectral studies and magnetic susceptibility studies.
References
- M. A. Halcrow, G. Cristou, “Nickel(II) Complexes with Tetra- and Pentadentate Aminopyridine Ligands” ,Chem. Rev.,vol. 94, pp.2421, 1994.
- C. Gosden, K. P. Healy, D. Pletcher, “Electrochemical and X-ray studies of nickel(II) Schiff base complexes,”J.Chem.Soc., Dalton Trans., pp. 972,1978.
- K. P. Healy, D. Pletcher, “Electroreductive intramolecular cyclization of bromoalkoxylated derivatives catalyzed by Nickel(I) Tetramethylcyclam in green media,”J. Organomet. Chem.,vol. 186, pp.401,1980.
- C. Gosden, J. B. Kerr, D. Pletcher, R. Rosas, “Comparative analysis of the electronic and EPR spectra of copper(II) and nickel(II) complexes,”J.Electroanal.Chem.InterefacialElectrochem.,vol.117,pp.101,1981.
- C. E. Dahm, D. G. Peters, “Ni(Salen) based polymer modified electrodes as sensors for metal ions,” J. Electroanal. Chem. Interefacial Electrochem.,vol. 406, pp.119, 1996.
- M. Mathew, G. J. Palenic, G. R. Clark, “Synthesis, spectral characterization, structural studies and biological investigations of transition metal complexes of some acid hydrazones” , J. Inorg. Chem., vol.12, pp.346, 1973.
- R. H. Holm, M. J. O. Conner, “Synthesis, spectral characterization and magnetic studies of studies of ternary nickel(II) complexes,” Inorg. Chem., vol.14 pp.408,1971.
- P. Bindu, M. R. P. Kurup, “ Synthesis, spectral characterization, structural studies and biological investigations of transition metal complexes,” ind. J. Chem., vol. 36A, pp.1094,1997.
- J.C.Donini, Hellebone, A. B. P. Lever, “Spectroscopic , electrochemical and biological studies of hydrazone complexes,”J.Am.Chem.Soc., vol.93,pp.6455,1971.
- R.D.Bereman,G. D. Shields,“Synthesis and characterization of square planar and pseudo-tetrahedral M(II)complexes,”Inorg. Chem.,vol. 18, pp. 946,1979.
- S. Balasubramanian, C. N. Krishnan, “An X-ray photoelectron spectroscopic study of some copper(II) tetraaza complexes,” Polyhedron, vol.5,pp. 669,1986.
- M. A. Ali, S. E. Livingstone, D. J. Phillips, "The chemistry of heterocyclic compounds,”Inorg. Chim. Acta, vol.6, pp. 39,1972.
- R. Pestorek, Z. Travnicek, E. Kvapilova, Z. Sindelar, F. Brezina, J. Marec, “Synthesis, spectral characterization and magnetic studies of studies of ternary nickel(II) complexes,”Polyhedron,vol. 18, pp. 151,1998.
- R. A. Eittah, M. Hamed, S. El. Makabaty, “Synthesis, spectral characterization, structural studies and biological investigations of transition metal complexes,” Trans. Met. Chem. ,vol.8, pp.198,1983.
- S. K. Jain. B. S. Garg, Y. K. Bhoon, “Magnetic and spectral studies of cobalt(II)chelates,”Trans. Met. Chem. ,vol.12, pp. 73,1987.
- A. Sreekanth, S. Sivakumar, M. R. P. Kurup, “Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine 2carbaldehyde,” J. Mol. Struct.,vol. 655 ,pp. 47,2003.
- B. S. Garg, M. R. P. Kurup, S. K. Jain, Y. K. Bhoon, “ Structural and spectral studies of novel Co(III) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde,” Transition Met. Chem.,vol. 16,pp. 111,1991.
- N. C. Kasuga, K. Sekino, C. Koumo, N. Shimada, M. Ishikawa, K. Nomiya, “Synthesis, structural characterization and antimicrobial activities of 4- and 6-coordinate nickel(II) complexes with three thiosemicarbazones and semicarbazone ligands,”J.Inorg. Biochem., vol.84, pp. 55, 2001.
- R. L. Dutta, A. Syamal, “Synthesis, characterization and 3D molecular modeling of some ternary complexes,” Elements of Magnetochemistry, vol. 2 pp.57,1993.
- C. Spinu, A. Kriza, “Co(II),Cu(II) and Ni(II) complexes of bidentate Schiff bases,” Acta Chim. Slov.,vol.47, pp.179,2000.