Vol. 12 No. 1 (2013): Mapana Journal of Sciences
Research Articles

Synthesis and Characterization of Photoluminescent PVA/ZnS: Mn2+ Nanocomposites

Priya L
Department of Physics, Centre for Postgraduate Studies, Jain University, III block Jayanagar, Bangalore-560 011

Published 2013-01-22

Keywords

  • Nanoparticles,
  • ZnS,
  • Mn2 ,
  • XRD,
  • Photoluminiscence

Abstract

A ZnS nanoparticle doped with Mn2+ is synthesized in aqueous media and PVA using chemical co-precipitation method. This colloid was analyzed using uv-vis spectrophotometry. It is observed that the absorption peak blue shifts as compared to the bulk absorption of ZnS suggesting the nanoparticle formation. The energy gaps of these nanoparticles were calculated from the uv-vis spectra. The average particle size analysis is carried out using XRD. Photoluminescence of PVA/ ZnS:Mn2+ is studied. It is observed that the composite sample exhibits an orange emission peak as is reported for pure ZnS: Mn2+.

References

  1. B. S. Rema Devi, R. Raveendran and A. V. Vaidyan, “Synthesis and characterization of Mn2+-doped ZnS nanoparticles,” Pramana, vol. 679, p. 68, 2007.
  2. H. C. Warad, S. C. Ghosh, B. Hemtanon, C. Thanachayanont and J. Dutta, “Luminescent nanoparticles of Mn doped ZnS passivated with sodium hexametaphosphate,” Scien. Technolog. Advan. Mater., vol. 6, p. 296, 2005. http://dx.doi.org/10.1016/j.stam.2005.03.006.
  3. J. C. Manifacier, M. D. Murcia, J. P. Fillard and E. Vicario, “Optical and electrical properties of SnO2 thin films in relation to their stoichiometric deviation and their crystalline structure,” Thin Solid Films, vol. 41, p. 127, 1977.
  4. K. K. Nanda, S. N. Sarangi, and S. N. Sahu, “CdS Nanocrystalline films: Composition, surface, crystalline size, structural and optical absorption studies,“ Nanostruct. Mater. vol. 10, p. 1401, 1998. http://dx.doi.org/10.1016/S0965-9773(99)00014-8.
  5. L. W. Wang and A. Zunger, “High-Energy Excitonic Transitions in CdSe Quantum Dots,” J. Phy. Chem. B, vol. 102, p. 6449, 1998. http://dx.doi.org/10.1021/jp981018n.
  6. M. A. Khader and B. Thomas, “Dc conductivity of nanoparticles of CdS and ZnS,” Nanostruct. Mater. vol. 10, p. 593, 1998. http://dx.doi.org/10.1016/S0965-9773(98)00100-7.
  7. O. A. Korotchenkov, A. Canterero, A. P. Shpak, Y. A. Kunitskii, A. I. Senkevich, M. O. Borovoy and A. B. Nadtochii, “Doped ZnS:Mn nanoparticles obtained by sonochemical synthesis,” Nanotechn., vol. 16, p. 2033, 2005. http://dx.doi.org/10.1088/0957-4484/16/10/008.
  8. S. K. Pandey, P. Verma and A. C. Pandey, Proc. ASID, vol. 259, p. 8, 2006.
  9. X. Fang, T. Zhai, U. K. Gautam, L. Li, L. Wu, Y. Bando and D. Goldberg, “ZnS nanostructures: From synthesis to applications,” Prog. Mater. Scien., vol. 56, p. 175, 2011. http://dx.doi.org/ 10.1016/j.pmatsci.2010.10.001.