Vol. 12 No. 2 (2013): Mapana - Journal of Sciences
Research Articles

H-bonded Chains and Networks: A Recurring Feature in the Solid State Structures of Manganese (III) Carboxylate Schiff Base Complexes

  • Biny Sasi,
  • Swathy S,
  • Thampidas V S,
  • Pike D Robert
Biny Sasi
Department of Chemistry, Sree Narayana College (DCSNC), Varkala, Kerala, India-695 145
Bio
Swathy S
Department of Chemistry, Sree Narayana College (DCSNC), Varkala, Kerala, India-695 145
Bio
Thampidas V S
Department of Chemistry, Sree Narayana College (DCSNC), Varkala, Kerala, India-695 145
Bio
Pike D Robert
Department of Chemistry, Sree Narayana College (DCSNC), Varkala, Kerala, India-695 145
Bio
DOI: https://doi.org/10.12723/mjs.25.2

Published 2021-08-27

Keywords

  • Manganese (III),
  • Carboxylate,
  • Schiff base,
  • H-bonds,
  • Chains,
  • Networks.
    • ...More
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Copyright (c) 2013

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Abstract

Two new manganese(III) Schiff base complexes,  [Mn(salen)(m-NO2-C6H4CO2)(H2O)] (1) and  [Mn(msalen) (p-OH-C6H4CO2)(H2O)] (2), where H2salen = N,N'-bis(salicylidene)-1,2-diaminoethane, H2msalen = N,N'-bis (3-methoxysalicylidene)-1,2-diaminoethane were synthesized from the manganese (II) carboxylates.  Single crystal X-ray diffraction studies show that the Jahn-Teller distorted octahedral complexes are stabilized by              H-bonded chains and networks in the solid state.  

References

  1. J. D. Dunitz, “Phase transitions in molecular crystals from a chemical viewpoint”, Pure Appl. Chem., vol. 63, No. 2, pp. 177-185, 1991. doi:10.1351/pac199163020177
  2. J. M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995.
  3. G. M. Whitesides and B. Grzybowski, “Self-Assembly at All Scales”, Science, vol. 295, pp. 2418-2421, 2002. doi:10.1126/science.1070821.
  4. J. M. Lehn, “From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry”, Chem. Soc. Rev., vol. 36, pp. 151-160, 2007. doi: 10.1039/b616752g
  5. D. J. Hoffart, J. Tiburcio, A. de la Torre, L. K, Knight and S. J. Loeb, “Cooperative Ion-Ion Interactions in the Formation of Interpenetrated Molecules”, Angew. Chem. Int. Ed., vol. 47 (1), pp. 97-101, 2007. doi: 10.1002/anie.200703019
  6. (6a)S. Adhikari, A. Uren and R. Roy, J. Biol. Chem., vol.283, pp. 1334-1339, 2008.
  7. (6b) Y. Mu and Y. Q. Gao, “Effects of hydrophobic and dipole-dipole interactions on the conformational transitions of a model polypeptide”, J. Chem. Phys., vol. 127, pp. 105102-105111, 2007.
  8. (6c) B. N. J. Persson and R. Ryberg, “Vibrational interaction between molecules adsorbed on a metal surface: The dipole-dipole interaction”, Phys. Rev. B, vol 24 (12), pp. 6954-6970, 1981.
  9. J. O' M. Bockris, K. N. Reddy and M. Gamboa-Aldeco, Modern Electrochemistry 1, Springer, Berlin, 2000.
  10. I. Kitaigorodski, Molecular Crystals and Molecules, Academic Press: New York, 1973.
  11. (9a) A. Sygula, F. R. Fronczek, R. Sygula, P. W. Rabideau and M. M. Olmstead, “A Double Concave Hydrocarbon Buckycatcher”, J. Am. Chem. Soc., vol. 129 (13), pp. 3842-3843, 2007.
  12. (9b) A. Petitjean, R. G. Khoury, N. Kyritsakas and J. -M. Lehn, “Dynamic Devices. Shape Switching and Substrate Binding in Ion Controlled Nanomechanical Molecular Tweezers”, J. Am. Chem. Soc., vol. 126, pp. 6637-6647, 2004.
  13. M. Albrecht, “Supramolecular chemistry-general principles and selected examples from anion recognition and metallosupramolecular chemistry”, Naturwissenschaften, vol. 94, pp. 951‐966, 2007. doi:10.1007/s00114-007-0282-7
  14. J. W. Steed, D. R. Turner, and K. J. Wallace, Core Concepts in Supramolecular Chemistry and Nanochemistry, John Wiley & Sons, Ltd, 2007.
  15. N. Aurangzeb, C. E. Hulme, C. A. McAuliffe, R. G. Pritchard, M. Watkinson, A. Garcia-Deibe, M. R. Bermejo and A. Sousa, “The crystal structure of [Mn(salpn)(acetate)]2(H2O)3; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]”, J. Chem. Soc. Chem. Commun., (20), pp. 1524-1526, 1992.
  16. N. Aurangzeb, C. E. Hulme, C. A. McAuliffe, R. G. Pritchard, M. Watkinson, M. R. Bermejo and A. Sousa, “Structurally diverse manganese(III) carboxylate complexes of N2O2 donor set symmetrical Schiff base ligands”, J. Chem. Soc. Chem. Commun., (18), pp. 2193-2195, 1994. doi:10.1039/C39940002193
  17. C. E. Hulme, M. Watkinson, M. Haynes, R. G. Pritchard, C. A. McAuliffe, N. Jaiboon, B. Beagley, A. Sousa, M. R. Bermejo and M. Fondo, “Structurally diverse manganese(III) complexes of tetradentate N2O2 Schiff-base ligands with ancillary carboxylate donors”, J. Chem. Soc. Dalton Trans., (11), pp. 1805-1814, 1997. doi:10.1039/A701216K
  18. C. Zhang and C. Janiak, “A carboxylato-supported alkoxo-bridged dimanganese(III) complex:bis( -benzoato-O:O')bis[3-(3-methoxysalicylideneamino) propanolato-O,N,O':O']dimanganese(III)” , Acta Cryst. C37, pp. 719-720, 2001.
  19. M. R. Bermejo, M. I. Ferna´ndez, A. M. Gonza´lez-Noya, M. Maneiro, R. Pedrido, M. J. Rodrı´guez, J. C. Garcı´a-Monteagudo and B. Donnadieu, “Novel peroxidase mimics: μ-Aqua manganese-Schiff base dimers”, J. Inorg. Biochem., vol.100 (9), pp. 1470-1478, 2006.
  20. S. Biswas, A. K. Dutta, K. Mitra, M. C. Dul, S. Dutta, C. R. Lucas and B. Adhikary, “Synthesis, characterization, electrochemical and magnetic studies on manganese(III) complexes involving bridging carboxylates”, Inorg. Chim. Acta, vol. 377 (1), pp. 56-61, 2011.
  21. P. Kar, R. Biswas, M. G. B. Drew, Y. Ida , T. Ishida and A. Ghosh, “Structure and magnetic properties of an unprecedented syn-anti μ-nitrito-1κO:2κO′ bridged Mn(III)-salen complex and its isoelectronic and isostructural formate analogue”, Dalton Trans., vol. 40, pp. 3295-3304, 2011. doi:10.1039/C0DT01521K
  22. P. Mukherjee, P. Kar, S. Ianelli and A. Ghosh, “Isolation of a novel intermediate during unsymmetrical to symmetrical rearrangement of a tetradentate Schiff base ligand in a manganese(III) complex: Catalytic activity of the rearranged product towards alkene epoxidation”, Inorg. Chim. Acta, vol. 365 (1), pp. 318-324, 2011.
  23. F. Benetollo, V. Peruzzo, S. Tamburini and P. A. Vigato, “Manganese complexes with acyclic compartmental Schiff bases”, Inorg. Chem. Commun., vol.15, pp. 84-87, 2012.
  24. V. S. Thampidas, T. Radhakrishnan and R. D. Pike, “Aqua{2,2-[ethane-1,2-diylbis(nitrilomethylidyne)] diphenolato}(3-nitrobenzoato) manganese(III)”, Acta Cryst. E64, pp. m990-m991”, 2008. doi:10.1107/S1600536808019715
  25. R. Reshma, P. V. Soumya, S. M. Simi, V. S. Thampidas and R. D. Pike, “Aqua{6,6'-dimethoxy-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)] diphenolato}(4-hydroxy benzoato) manganese(III)” Acta Cryst. E65, pp. m1110-m1111, 2009. doi:10.1107/ S1600536809032553
  26. G. M. Sheldrick, “Programs for Crystal Structure Analyses”, SHELX-97 (SHELXS 97 and SHELXL 97), University of Göttingen, Germany, 1998.
  27. C. F. Macrae, P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor, M. Towler and J. van de Streek, “Mercury: visualization and analysis of crystal structures”, J. Appl. Cryst., 39, pp. 453-457, 2006. doi:10.1107/S002188980600731X
  28. M. Á. Vázquez-Fernández , M. I. Fernández-García , A. M. González-Noya, M. Maneiro , M. R. Bermejo and M. J. Rodríguez-Doutón, “Supramolecular networks of Mn(III)–Schiff base complexes assembled by nitrate counterions: X-ray crystal structures of 1D chains and 2D networks”, Polyhedron, vol. 31(1), pp 379, 2012.
  29. P. Bhowmik, H. P. Nayek, M. Corbella, N. Aliaga-Alcalde and S. Chattopadhyay, “Control of molecular architecture by steric factors: mononuclear vs polynuclear manganese(III) compounds with tetradentate N2O2 donor Schiff bases”, Dalton Trans., vol. 40, pp. 7916-7926, 2011. doi:10.1039/C0DT01723J