Vol. 24 No. 1 (2025): Mapana Journal of Sciences
Research Articles

Effect of Synthetic and Natural Chelating Agent on Yttrium Iron Garnet (YIG) Nanocrystalline Powder via Sol Gel Method

M. Asisi Janifer
Department of Physics, Stella Maris College (Autonomous), Chennai - 600086, India
S. Anand
Department of Polymer Science and Engineering Korea National University, Chungju 27469, Republic of Korea
M. Muralidharan
Department of Physics, S. A. Engineering College, Chennai-600077, India
M. Senthuuran
Department of Physics, Loyola College, Chennai -600034, India
S. Pauline
Department of Physics, Stella Maris College (Autonomous), Chennai -600086, India

Published 2025-04-05

Keywords

  • Garnet,
  • Chelating agents,
  • HRSEM,
  • VSM,
  • Dielectric studies

Abstract

The influence of synthetic and natural chelating agents on the structure, morphology, and magnetic properties of pure Yttrium Iron Garnet (Y3Fe5O12) is examined. YIG samples are manufactured utilizing the synthetic chelating agent citric acid and the natural chelating agent lemon extract at varying temperatures. The generated samples are examined by X-ray Diffraction analysis (XRD). The X-ray Diffraction Pattern (XRD) revealed the garnet phase of nano ferrites at elevated temperatures. The morphological characteristics and elemental composition of the YIG samples are examined using High-Resolution Scanning Electron Microscopy (HRSEM) and Energy-dispersive X-ray Spectroscopy (EDAX), respectively. Metal oxide vibrations (M-O) and active Raman modes are analysed using Fourier Transform Infrared spectroscopy (FTIR) and Raman spectroscopy. The room-temperature magnetic characteristics of YIG samples are examined using a Vibrating Sample Magnetometer (VSM). The dielectric constant and dielectric loss of the nanomaterial are examined across multiple frequencies at varied temperatures.

References

  1. S Nasir, M Anisur Rehman and Muhammad Ali Malik, Structural and dielectric properties of Cr-doped Ni–Zn nanoferrites, Phys. Scr. 83 (2011) 025602 (5pp), doi:10.1088/0031-8949/83/02/025602.
  2. MajidNiazAkhtar, Muhammad Azhar Khan, Mukhtar Ahmad, G. Murtaza, R.Raza, S. F. Shaukat, M. H. Asif, G. Abbas, M. S. Nazir, M. R.Raza, Y3Fe5O12 nanoparticulate garnet ferrites: Comprehensive study on the synthesis and characterization fabricated by various routes, Journal of Magnetism and Magnetic Materials, S0304-8853(14)00519-8,doi: 10.1016/j.jmmm.2014.06.004.
  3. Ftema W. Aldbea, N.B.Ibrahim and M. Yahya,Effect of adding aluminum ion on the structural, optical, electrical and magneticproperties of terbium doped yttrium iron garnet nanoparticles filmsprepared by sol-gel method, Applied Surface Science (2014), doi:10.1016/j.apsusc.2014.10.019.
  4. Majid Niaz Akhtar, A.B. Sulong, Mukhtar Ahmad, Muhammad Azhar Khan, Akbar Ali, Impacts of Gd-Ce on the Structural, Morphological and Magnetic Properties of Garnet Nanocrystalline Ferrites Synthesized via Sol-gel Route, Journal of Alloys and Compounds, S0925-8388(15)31702-3 doi: 10.1016/j.jallcom.2015.11.146.
  5. Wang Minqiang , Zhu Xiangying , Wei Xiaoyong, Zhang Liangying& Yao Xi, Preparation and annealing process of Y3Fe5O12 by sol gel method,Ferroelectrics 5. 2001. Vol. 263. pp. 249-254, doi:10.1080/00150190108008577.
  6. L. Fernandez-Garcia, M. Suarez, J.L. Menendez, Synthesis of mono and multidomain YIG particles by chemical coprecipitation or ceramic procedure, Journal of Alloys and Compounds 495 (2010) 196–199, doi:10.1016/j.jallcom.2010.01.119.
  7. P. Vaqueiro and M. A. Lo´pez-Quintela, Influence of Complexing Agents and pH on Yttrium-Iron Garnet Synthesized by the Sol-Gel Method, Chem. Mater. 1997, 9, 2836-2841.
  8. Coutinho, D.M. and Verenkar, V.M.S., 2019. Spin canting and surface spin disorder in Ni substituted Co-Cd ferrite nanoparticles synthesized by fuel deficient combustion method. Journal of Alloys and Compounds, 782, pp.392-403.
  9. Soufi, A., Hajjaoui, H., Elmoubarki, R., Abdennouri, M., Qourzal, S. and Barka, N., 2021. Spinel ferrites nanoparticles: Synthesis methods and application in heterogeneous Fenton oxidation of organic pollutants–A review. Applied Surface Science Advances, 6, p.100145.
  10. S. Hosseini Vajargah, H.R. Madaah Hosseini , Z.A. Nemati, Synthesis of nanocrystalline yttrium iron garnets by sol–gel combustion process: The influence of pH of precursor solution, Materials Science and Engineering B 129 (2006) 211–215, doi:10.1016/j.mseb.2006.01.014.
  11. S. Anand, A. Persis Amaliya, M. Asisi Janifer and S. Pauline, Structural, Morphological and Dielectric studies of Zirconium substituted CoFe2O4 nanoparticles, Modern Electronic Materials, doi:10.1016/j.moem.2017.10.001
  12. N. Rodziah, M. Hashim, I.R. Idza, I. Ismayadi, A.N. Hapishah, M.A. Khamirul, Dependence of developing magnetic hysteresis characteristics on stages of evolving microstructure in polycrystalline yttrium iron garnet, Applied Surface Science 258 (2012) 2679– 2685, doi:10.1016/j.apsusc.2011.10.117.
  13. M. Niyaifar , H. Mohammadpour, M. Dorafshani, A. Hasanpour, Size dependence of non-magnetic thickness in YIG nanoparticles, Journal of Magnetism and Magnetic Materials 409 (2016) 104–110, doi.org/10.1016/j.jmmm.2016.02.097.
  14. Nadeem Nasir, NoorhanaYahya, Muhammad Kashif, HanitaDaud,MajidNiazAkhtar, HasnahMohdZaid, AfzaShafie, and Lee Chaw Teng, Observation of a Cubical-Like Microstructure of Strontium Iron Garnet and Yttrium Iron Garnet Prepared via Sol–Gel Technique, Journal of Nanoscience and Nanotechnology ,Vol. 11, 2551–2554, 2011, doi:10.1166/jnn.2011.2724.
  15. A.M. abdeen, Dielectric behaviour in Ni—Zn ferrites J. Magn. Magn. Mater. 199 (1999) 121–129. doi:10.1016/S0304-8853(98)00324-2.
  16. MajidNiazAkhtar, A. Rahman, A.B. Sulong, Muhammad Azhar Khan, Structural, Spectral, Dielectric and Magnetic Properties of Ni0.5MgxZn0.5-xFe2O4 Nanosized ferrites for Microwave absorption and High Frequency Applications, Ceramics InternationalS0272-8842(16)32348-3,doi : 10.1016/j.ceramint.2016.12.081.
  17. LalithaSirdeshmukh, K Krishna Kumar, S Ballaxman, A Rama Krishna and G Sathaiah, Dielectric properties and electrical conduction in yttrium iron garnet (YIG), Mater. Sci., Vol. 21, No. 3, June 1998, pp. 219-226.
  18. WanFahmin Faiz Ali,NorazharuddinShahAbdullah, MaslindaKamarudin, MohdFadzilAin , ZainalArifin Ahmad, Sintering and grain growth control of high dense YIG, Ceramics International (2016), .doi:10.1016/j.ceramint.2016.06.004.
  19. Rabia Ahmad, IftikharHussainGul, Muhammad Zarrar, Humaira Anwar, Muhammad Bilal khan Niazi, Azim Khan, Improved Electrical Properties of Cadmium Substituted Cobalt Ferrites Nano-particles for Microwave Application, Journal of Magnetism and Magnetic MaterialsS0304-8853(15)30885-4,doi: 10.1016/j.jmmm.2015.12.019.
  20. Majid Niaz Akhtar, A. Rahman, A.B. Sulong, Muhammad Azhar Khan, Structural, Spectral, Dielectric and Magnetic Properties of Ni0.5MgxZn0.5-xFe2O4 Nanosized ferrites for Microwave absorption and High Frequency Applications, Ceramics InternationalS0272-8842(16)32348-3,doi : 10.1016/j.ceramint.2016.12.081.
  21. SaberE. Mansour, 1 2Monalisa Pattanayak and 2P. L. Nayak, Green Synthesis of Gold Nano Particles VII: Green Synthesis and Characterization of Gold Nano Particles Using the Extract of Lemon (Citrus limon) and Study of its Cytotoxicity Properties, Middle-East Journal of Scientific Research 22 (2): 313-319, 2014,doi: 10.5829/idosi.mejsr.2014.22.02.21877.
  22. Kristina. Penniston, M.D.,Stephen Y. Nakada, M.D.,Ross P. Holmes and Dean G. Assimos, M.D, Quantitative Assessment of Citric Acid in Lemon Juice, Lime Juice, and Commercially-Available Fruit Juice Products,journal of endourology Volume 22, Number 3, March 2008, doi: 10.1089/end.2007.0304.