Mapping Shockley-Read-Hall (SRH) lifetimes with differential photo conductance in Gallium Arsenide solar cells: effect of absorber thickness and electron hole lifetime asymmetry
Published 2025-12-01
Keywords
- Solar cells,
- SRH lifetime,
- photo conductance,
- photocurrent
Copyright (c) 2025

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Abstract
Recombination degrades a solar cell. Shockley-Read-Hall (SRH) recombination occurs in a solar cell due to the presence of defects. Defects control the lifetime of electrons and holes, and in a good solar cell these lifetimes should be as high as possible. Thus, it is a priority to know the SRH lifetimes in a working solar cell with good precision. Only if the lifetimes are measured properly can a protocol on how to increase them by minimizing the defects be followed. Standard methods are available which extracts SRH lifetimes from solar cell test structures. In this work, we use a method which is less costly and complex and applies to solar cells directly rather than test structures. In a GaAs PIN solar cell, we study how a varying absorber thickness and electron hole lifetime asymmetry affect this method, and we suggest a way to read the SRH lifetimes from graphs of simply processed experimental data. A method to find the SRH lifetime for any absorber thickness between 1–100 μm is proposed.
References
- Wilson, G. M., Al-Jassim, M., Metzger, W. K., Glunz, S. W., Verlinden, P., Xiong, G., Mansfield, L. M., Stanbery, B. J., Zhu, K., & Yan, Y., The 2020 Photovoltaic Technologies Roadmap. Journal of Physics D: Applied Physics, 53, 493001, 2020. DOI: 10.1088/1361-6463/ab9c6a.
- Lee, T. D., & Ebong, A. U., A Review of thin-film Solar Cell Technologies and Challenges. Renewable and Sustainable Energy Reviews, 70, 1286-1297, 2017. DOI: https://doi.org/10.1016/j.rser.2016.12.028.
- Kirchartz, T., & Rau, U., What makes a Good Solar Cell? Advanced Energy Materials, 8, 1703385, 2018. DOI: https://doi.org/10.1002/aenm.201703385
- R. F. Pierret, Semiconductor Device Fundamentals, Addison-Wesley Publishing Company, 1996
- D. E. Carlson and C. R. Wronski, Amorphous silicon solar cell, Appl. Phys. Lett. 28, 671-673, 1976. DOI: https://doi.org/10.1063/1.88617.
- A. H. Pawlikiewicz and S. Guha, Numerical Modeling of an Amorphous-Silicon-Based p-i-n Solar Cell, IEEE Trans. Electron Devices 37, 403-409, 1990. DOI: https://doi.org/10.1109/16.46374.
- S. Zhou, J. Sun, C. Zhou and Z. Deng, Comparison of recombination models in organic bulk heterojunction solar cells, Physica B 415, 28, 2013 https://doi.org/10.1016/j.physb.2013.01.030
- R. Gogolin and N. P. Harder, Trapping behavior of Shockley-Read-Hall recombination centers in silicon solar cells, Journal of Applied Physics 114, 064504, 2013. DOI: https://doi.org/10.1063/1.4817910
- S. Zeiske, O. J. Sandberg, N. Zarrabi, W. Li, P. Meredith, and A. Armin, Direct observation of trap assisted recombination in organic photovoltaic devices, Nature Communications 12, 3603, 2021. https://www.nature.com/articles/s41467-021-23870-x
- S. Ryu, N. Y. Ha, Y. H. Ahn, J. Y. Park, and S. Li, Light intensity dependence of organic solar cell operation and dominance switching between Shockley-Read-Hall and bimolecular recombination losses, Scientific Reports 11, 16781, 2021. https://www.nature.com/articles/s41598-021-96222-w
- P Calado, D Burkitt, Z Yao, J Troughton, T M Watson, M J Carnie, A M Telford, B C O Regan, J Nelson, and P R F Barnes, Identifying dominant recombination mechanisms in perovskite solar cells by measuring the transient ideality factor, Physical Review Applied 11, 044005, 2019. DOI: https://doi.org/10.1103/PhysRevApplied.11.044005.
- S. Grover, J. V. Li, D. L. Young, P. Stradins, and H. M. Branz, Reformulation of solar cell physics to facilitate experimental separation of recombination pathways, Applied Physics Letters 103, 093502, 2013. DOI: https://doi.org/10.1063/1.4819728
- J. Hubin and A. V. Shah, Effect of the recombination function on the collection in a PIN solar cell, Philosophical Magazine B 72, 589, 1995.
- R. A. Sinton and A. Cuevas, Contactless determination of current voltage characteristics and minority carrier lifetimes in semiconductors from quasi steady state photoconductance data, Appl. Phys. Letters 69, 2510, 1996. doi: 10.1063/1.117723
- M. Juhl, C. Chan, M. D. Abbott, and T. Trupke, Anomalously high lifetimes measured by quasi steady state photoconductance in advanced solar cell structures, Appl. Phys. Lett. 103, 243902, 2013. doi: 10.1063/1.4840337
- I. Martin, A. Alcaniz, A. Jimenez, G. Lopez, C. D. Canizo, and A Datas, Application of quasi steady state photoconductance technique to lifetime measurements on crystalline germanium substrates, IEEE Journal of photovoltaics 10, 1068, 2020. DOI: 10.1109/JPHOTOV.2020.2981839
- B. Grimm, S. J. Wolter, and J. Schmidt, Contactless quasi steady state photoconductance characterization of metal halide perovskite thin films, Scientific Reports 13, 11163, 2023. https://doi.org/10.1038/s41598-023-37745-2.
- R. K. Ahrenkiel, Measurement of minority carrier lifetime by time resolved photoluminescence, Solid State Electronics 35, 239, 1992. https://doi.org/10.1016/0038-1101(92)90228-5
- A. A. B. Baloch, F. H. Alharbi, G. Grancini, M. I. Hossain, M. K. Nazeeruddin, and N. Tabet, Analysis of Photocarrier Dynamics at Interfaces in Perovskite Solar Cells by Time Resolved Photoluminescence, The Journal of Physical Chemistry C 122, 47, 2018. https://pubs.acs.org/doi/10.1021/acs.jpcc.8b07069
- S. Shirakata and T. Nakada, Time resolved photoluminescence in Cu(In,Ga)Se2 thin films and solar cells, Thin Solid Films 515, 6151, 2007. DOI: 10.1016/j.tsf.2006.12.040
- A. W. Stephens, A. G. Aberle, and M. A. Green, Surface recombination velocity measurements at the silicon silicon dioxide interface by microwave detected photoconductance decay, Journal of Applied Physics 76, 363, 1994. DOI: 10.1063/1.357082
- K. Lauer, A. Laades, H. Ubensee, H. Metzner, and A. Lawerenz, Detailed analysis of the microwave detected photoconductance decay in crystalline silicon, Journal of Applied Physics 104, 104503, 2008. DOI: 10.1063/1.3021459
- A. N. Roy Choudhury, Quantifying SRH recombination in GaAs PIN solar cells, International Journal of Engineering Science Technologies 9(3), 60, 2025. https://doi.org/10.29121/ijoest.v9.i3.2025.703
- A. Imran, M. Sulaman, Y. Song, D. Eric, M. N. Zahid, M. Yousaf, M. I. Saleem, M. Li, and D. Li, Modelling and simulation of high efficiency GaAs PIN solar cells, Journal of Computational Electronics 20, 310, 2020. https://link.springer.com/article/10.1007/s10825-020-01583-6.
- H. J. Jo, Y. H. Mun, J. S. Kim, and S. J. Lee, Dependence on the incident light power of the internal electric fields in a GaAs PIN solar cell according to bright photoreflectance spectroscopy, Journal of the Korean Physical Society 69, 80, 2016. DOI: 10.3938/jkps.69.80
- S. J. Lee, H. J. Jo, M. G. So, C. W. Sohn, I. S. Han, J. S. Kim, I. H. Bae, S. J. Lee, S. K. Noh, H. Choi, and J. Y. Leem, Investigation of internal electric fields in GaAs solar cell under highly concentrated light, Journal of the Korean Physical Society 66, 667, 2015. DOI: 10.3938/jkps.66.667
- G. S. Sahoo and G. P. Mishra, Use of hetero intrinsic layer in GaAs PIN solar cell to improve the intermediate band performance, Materials Science and Engineering B 263, 114862, 2021. https://doi.org/10.1016/j.mseb.2020.114862
- O. J. Sandberg, J. Kurpiers, M. Stolterfoht, D. Neher, P. Meredith, S Shoaee and A. Armin, On the question of the need for a built in potential in perovskite solar cells, Advanced Material Interfaces 2000041, 2020. DOI:
- https://doi.org/10.1002/admi.202000041
- M. Limpinsel, A Wagenpfahl, M Mingebach, C Deibel, and V Dyakonov, Photocurrent in bulk heterojunction solar cells, Physical Review B 81, 085203, 2010. DOI: https://doi.org/10.1103/PhysRevB.81.085203.
- Z. E. Ooi, R. Jin, J. Huang, Y. F. Loo, A. Sellinger, and J. C. DeMello, On the pseudo-symmetric current-voltage response of bulk heterojunction solar cells, Journal of Materials Chemistry 18, 1644, 2008. https://pubs.rsc.org/en/content/articlelanding/2008/jm/b718563d.
- D. J. Wehenkel, L. J. A. Koster, M. M. Wienk, and R. A. J. Janssen, Influence of injected charge carriers on photocurrents in polymer solar cells, Physical Review B 85, 125203, 2012. DOI: https://doi.org/10.1103/PhysRevB.85.125203.
- G. F. A. Dibb, T. Kirchartz, D. Credgington, J. R. Durrant, and J. Nelson, Analysis of the relationship between linearity of corrected photocurrent and the order of recombination in organic solar cells, Journal of Physical Chemistry Letters 2, 2407, 2011. dx.doi.org/10.1021/jz201104d
- L. Liu & G. Li, Investigation of recombination loss in organic solar cells by simulating intensity dependent current voltage measurements, Solar Energy Materials & Solar Cells 95, 2557, 2011. doi:10.1016/j.solmat.2011.02.034
- M. Lenes, M. Morana, C. J. Brabec, and P. W. M. Blom, Recombination limited photocurrents in low band gap polymer/fullerene solar cells, Advanced Functional Materials 19, 1106, 2009. DOI: 10.1002/adfm.200801514
- J. Gray, X. Wang, R. V. K. Chavali, X. Sun, A. Kanti, and J. R. Wilcox, ADEPT 2.1, 2015. https://nanohub.org/resources/adeptnpt.