Published 2023-12-13
Keywords
- Zinc Oxide nano particles,
- Carbaryl pesticide,
- photodegradation,
- Ultra Violet irradiation
Copyright (c) 2023
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Abstract
Nano zinc oxide (ZnO) is a highly promising nano metal oxide that has found application in a wide range of areas, including fire retardancy, wrinkle reduction, and antimicrobial properties, among others. The wet chemical process was employed to synthesise nano zinc oxide, with Zinc nitrate hexahydrate as the precursor. The synthesised nano ZnO powder underwent characterization in order to determine its shape and physical properties and was employed for the purpose of photodegradation of a solution containing the Carbaryl insecticide. The experiment involved the utilisation of a set concentration of 5 ppm Carbaryl pesticide and a catalyst consisting of 5mg/L nano ZnO. The resulting mixture was then subjected to photodegradation through exposure to UV irradiation. The degradation of the pesticide was shown to occur at a rate of 95% within a 60-minute timeframe. The results demonstrate the significant photocatalytic degradation activity exhibited by the nano ZnO particles that were synthesised.
References
- D. Gola, A. Kriti, N. Bhatt, M. Bajpai, A. Singh, A. Arya, N. Chauhan, S. K. Srivatsava, P.K. Tyagi, Y. Agarwal, Curr Res Green Sustainable Chemistry 4 (2021).
- J. Fenik, M. Tankiewicz, M. Biziuk, Properties and determination of pesticides in fruits and vegetables, Trends in Analytical Chemistry 30, 6 (2011).
- S. Mostafalou, M. Abdollahi, Pesticides and human chronic diseases: Evidences, mechanisms, and perspectives, Toxicology and Applied Pharmacology 268 (2013).
- D. B. Barr, L. L. Needham, Analytical methods for biological monitoring of exposure to pesticides: a review, Journal of Chromatography B 778 (2002).
- D. J. Ecobichon, Carbamate insecticides. In: Krieger R (ed). Handbook of Pesticide Toxicology. San Diego, CA: Academic Press (2001).
- S. P Dalai , S. Ampolu , U. Hanumanthu , AVLNH Hariharan. Impacts of Effluents from Plastic waste on Environment and Precautions. Chemical Science Review and Letters. 11 (41), 356-359(2022)
- P Logeswari , S Silambarasan , A Jayanthi. Synthesis of silver nanoparticles using plants extract and analysis of their antimicrobial property. J Saudi Chem Soc. 19(31) 1(2015).
- S Ampolu, U Hanumanthu, D.S. Priya, AVLNSH Hariharan, MVV Ramanjaneyulu. Greener Protocol for the Synthesis of Carbamates. Journal of Scientific Research, 15 (2), 481-488(2023).
- M. J. Hajipour, K.M. Fromm, A.A. Ashkarran, et al. Antibacterial properties of nanoparticles. Trends Biotechnol. 30, 499 (2012).
- M. Eddleston, Poisoning by pesticides. Medicine 48, 3 (2020)
- Z. Q. Jia, Y.C. Zhang, Q.T. Huang, A. K. Jones, Z. J. Han, C. Q. Zhao, Acute toxicity, bioconcentration, elimination, action mode and detoxification metabolism of broflanilide in zebrafish, Danio rerio. Journal of Hazardous Materials 394, (2020). https://doi.org/10.1016/j.jhazmat.2020.122521 122521.
- M. Sittig. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nd ed. Noyes Publications, Park Ridge, NJ. (1985).
- U. S. Environmental Protection Agency. Health and Environmental Effects Profile for Carbaryl. EPA/600/x84/155. Environmental Criteria and Assessment Office, Office of Health and Environmental Assessment, Office of Research and Development, Cincinnati, OH. (1984).
- The Merck Index. An Encyclopedia of Chemicals, Drugs, and Biologicals. 11th ed. Ed. S. Budavari. Merck and Co. Inc., Rahway, NJ. (1989).
- U. S. Department of Health and Human Services. Hazardous Substances Data Bank (HSDB, online database). National Toxicology Information Program, National Library of Medicine, Bethesda, MD. (1993).
- U. S. Department of Health and Human Services. Registry of Toxic Effects of Chemical Substances (RTECS, online database). National Toxicology Information Program, National Library of Medicine, Bethesda, MD. (1993).
- U. S. Environmental Protection Agency. Integrated Risk Information System (IRIS) on Carbaryl. National Center for Environmental Assessment, Office of Research and Development, Washington, DC. (1999).
- M. H. Pereza, G. Penuela, M. I. Maldonado, O. Malato, P. Fernandez Ibanez, I. Oller, W. Gernjak, S. Malato, Degradation of pesticides in water using solar advanced oxidation processes. Applied Catalysis B Enviromental 64 (2006).
- S. Gafar Muhamad, Kinetic studies of catalytic photodegradation of chlorpyrifos insecticide in various natural waters. Arab Journal of Chemistry 3, 2 (2010).
- M. Abdennouri, A. Galadi, N. Barka, M. Baalala, K. Nohair, M. Elkrati, M. Sadiq, M. Bensitel, Synthesis, characterization and photocatalytic activity by para-chlorotoluene photooxidation of tin oxide films deposited on Pyrex glass substrates. Physical Chemical News. 54, (2010).
- S. Ampolu, D. S. Priya, MVV. Ramanjaneyulu, U Hanumanthu, A Kumar. Repercussions of Chemical Fertilizers on the Environment and Safety Measures, Biological Forum – An International Journal, 15(2), 1262-1268(2023)
- A. Satheesh , H. Usha , M. Visalakshi , T. Rambabu , Ch.V.V.Srinivas, Y. Vamsi Kumar, S. Paul Douglas, Nano copper ferrite catalyzed one pot synthesis and microbial studies of chalcone derivatives, International Journal of Engineering, Research and Technology 6, 5, (2017).
- S.G.A. Josephine, A. Sivasamy, Indian Journal of Chemistry, 59A (2020).
- N. Barka, S. Qourzal, A. Assabbane, A. Nounah, Y. AitIchou, Photocatalytic degradation of an azo reactive dye, reactive yellow 84, in water using an industrial titanium dioxide coated media. Arab Journal Chemistry 3, (2010).
- S. Vasamsetty, S. Medidi, S. Ampolu, et al. Catalyst Free One-Pot Synthesis of Chromeno Quinolines and Their Antibacterial Activity, Green and Sustainable Chemistry . 7 (2)141-151 (2017) DOI: 10.4236/gsc.2017.72011.
- S. Ampolu, H. Usha. Nano ZnO is a suitable and effective catalyst for the synthesis of 2,4,6-Triarylpyridines from Chalcones,2019 International Journal Of Research Culture Society, 3, 11(2019).
- S. Anandan, A. Vinu, K. L. P. S. Lovely, N. Gokulakrishnan, P. Srinivasu, T. Mori, V. Murugesan, K. Ariga, Journal of Molecular Catalysis A Chemistry, 266 (2007).
- A. Satheesh, H. Usha, Synthesis of Triarylpyridine derivatives using Nano ZnO, Chemical science Reviews and Letters,8, 32 (2019).
- J. Zhang, Z. P. Peng, A. Soni, Y. Zhao, Y. Xiong (2011) Raman spectroscopy of fewquintuple layer topological insulator Bi2Se3 nanoplatelets. Nano Letters 11(2011)
- M. N. Alshabanat, M. M. Al-Anazy, Journal of Chemistry, (2018).
- S. Ampolu, D. S. Priya , U Hanumanthu, AVLNSH. Hariharan. Structural and Photoluminescence Properties of Si-doped ZnO Thin Films. Journal of Chengdu University of Technology. 26, 8 (2021)
- M. W. Lekota, K. M. Dimple, P. N. Nomngongo, Journal of Analytical Science and Technology, 10 (2019).
- Ch. Komali, N. Murali, K. Rajkumar, A. Ramakrishna, S. Yonatan Mulushoa, D. Parajuli, P. N. V. V. L. Pramila Rani, Satheesh Ampolu, K. Chandra Mouli, Y. Ramakrishna. Probing the dc electrical resistivity and magnetic properties of mixed metal oxides Cr3+ substituted Mg–Zn ferrites. Chemical Papers. 77, 1, 109–117 https://doi.org/10.1007/s11696-022-02466-9
- S. Ampolu, U. Hanumantu. A Greener and Rapid Approach for Synthesis of Pyranopyrroles using Nano ZnO as an efficient Catalyst. Int J Res Appl Sci & Engg Tech. 7(9)661-666(2019) https://doi.org/ 10.22214/ijraset.2019.10101.
- A. J. Salazar-Perez, M. A. Camacho-Lopez, R. A. Morales-Luckie, V. Sanchez-Mendieta (2005) Structural evolution of Bi2O3 prepared by thermal oxidation of bismuth nano particles. Superficies y Vacio 18 (2005).
- H. A. Kiwaan, T. M.Atwee, E. A. Azab and A. A. El-Bindary, Journal of Molecular Structure, 1200, Article 127115 (2020).
- A. Rafiq, M. Ikram, S. Ali, F. Niaz, M. Khan, Q. Khan, M. Maqbool, Journal of Industrial and Engineering Chemistry 97 (2021).
- M.S. Geetha, H. Nagabhushana, H.N. Shivananjaiah, Green mediated synthesis and characterization of ZnO nanoparticles using Euphorbia Jatropa latex as reducing agent, Journal of Science: Advanced Materials and Devices 1, (2016).
- M. Sudheere, G. Ravinder, G. Ravi, P. Venkataswamy, K. Vaishnavi, N. Chittibabu and M. Vithal, Indian Journal of Chemistry 59A (2020).
- D. K. Bhole, R.G. Puri, P. D. Meshram and R.S. Sirsam, Journal of Indian Chemical Society 97 (2020).
- E. M. Samsudin, S. N. Gho, T. Y. Wu, T. T. Ling, S. B. A. Hamid and J. C. Juan, Sains Malays 44, 7 (2015).
- R. R. Mathiarasu, A. Manikandan, K. Panneerselvam, M. George, K. K. Raja, M. A. Almessiere, Y. Slimani, A. Baykal, A. Ansari, T. Kamal and A. Khan, Journal of Material Research and Technology 15 (2021).
- K. Qi , J. Yu, Interface Science and Technology 31 (2020).
- S. A. A. Anaam, H. Saim, M. Z. Sahdan and A. Al-Gheethi, International Journal of Nanoelectronics and Materials 12 (2019).
- M. Kus, S. Ribbens, V. Meynen and P. Cool, Catalyst 3 (2013).
- K. Byrappa, A. K. Subramani, S. Ananda, K. M .L. Rai, R. Dinesh and M. Yoshimura, Bull Material Science 29 (2006).
- Q. Zeng, Y. Liu, L. Shen, H. Lin, W. Yu, Y. Xu, R. Li and L. Huang, Journal of Colloid Interface Science 582 (2021).
- N.I.K. Dhanjal, P. Kaur, D. Sud, S. S. Cameotra, Water Environment Research 86 (2014).